{"id":160421,"date":"2023-09-27T14:03:42","date_gmt":"2023-09-27T08:33:42","guid":{"rendered":"https:\/\/www.gkseries.com\/blog\/?p=160421"},"modified":"2023-09-27T14:03:54","modified_gmt":"2023-09-27T08:33:54","slug":"the-reaction-of-pcl3-with-phli-in-13-molar-ratio-yields-x-as-one-of-the-products","status":"publish","type":"post","link":"https:\/\/www.gkseries.com\/blog\/the-reaction-of-pcl3-with-phli-in-13-molar-ratio-yields-x-as-one-of-the-products\/","title":{"rendered":"The reaction of PCl3 with PhLi in 1:3 molar ratio yields X as one of the products"},"content":{"rendered":"\n<p>Q. The reaction of PCl3 with PhLi in 1:3 molar ratio yields <strong>X <\/strong>as one of the products, which on further treatment with CH3I gives <strong>Y<\/strong>. The reaction of <strong>Y <\/strong>with <em>n<\/em>-BuLi gives product <strong>Z<\/strong>. The products <strong>X<\/strong>, <strong>Y <\/strong>and <strong>Z<\/strong>, respectively, are<\/p>\n\n\n\n<p>(A) [PPh4]Cl, [Ph2P=CH2] and Ph2P(<em>n<\/em>-Bu)<\/p>\n\n\n\n<p>(B) PPh3, [Ph3PI](CH3) and Ph2P(<em>n<\/em>-Bu)3<\/p>\n\n\n\n<p>(C) PPh3, [Ph3P(CH3)]I and Ph3P=CH2<\/p>\n\n\n\n<p>(D) [PPh4]Cl, [Ph3P=CH2] and [Ph3P(<em>n<\/em>-Bu)]Li<\/p>\n\n\n\n<p>Ans: PPh3, [Ph3P(CH3)]I and Ph3P=CH2<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Q. The reaction of PCl3 with PhLi in 1:3 molar ratio yields X as one of the products, which on further treatment with CH3I gives Y. The reaction of Y with n-BuLi gives product Z. The products X, Y and Z, respectively, are (A) [PPh4]Cl, [Ph2P=CH2] and Ph2P(n-Bu) (B) PPh3, [Ph3PI](CH3) and Ph2P(n-Bu)3 (C) PPh3, [&hellip;]<\/p>\n","protected":false},"author":419,"featured_media":160425,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[5141],"tags":[5140],"class_list":["post-160421","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-gate","tag-gate-questions"],"_links":{"self":[{"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/posts\/160421","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/users\/419"}],"replies":[{"embeddable":true,"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/comments?post=160421"}],"version-history":[{"count":1,"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/posts\/160421\/revisions"}],"predecessor-version":[{"id":160423,"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/posts\/160421\/revisions\/160423"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/media\/160425"}],"wp:attachment":[{"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/media?parent=160421"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/categories?post=160421"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.gkseries.com\/blog\/wp-json\/wp\/v2\/tags?post=160421"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}