MCQs on Class 11 Chemistry Chapter 4 Chemical Bonding and Molecular Structure

(1) In which of the following molecule/ion all the bonds are not equal?
[A] XeF4
[B] BF4-
[C] C2H4
[D] SiF4
Answer: C2H4
(2) Which molecule/ion out of the following does not contain unpaired electrons?
[A] N2+
[B] O2
[C] O22-
[D] B2
Answer: O22-

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(3) Number of π bonds and σ bonds in the following structure is–

[A] 6, 19
[B] 4, 20
[C] 5, 19
[D] 5, 20
Answer: 5, 19
(4) Which of the following species has tetrahedral geometry?
[A] BH4-
[B] NH2-
[C] CO32-
[D] H3O+
Answer: BH4-
(5) In NO3-ion, the number of bond pairs and lone pairs of electrons on the nitrogen atom is
[A] 2, 2
[B] 3, 1
[C] 1, 3
[D] 4, 0
Answer: 4, 0
(6) In PO43- ion the formal charge on the oxygen atom of P–O bond is
[A] + 1
[B] – 1
[C] – 0.75
[D] + 0.75
Answer: – 1
(7) Hydrogen bonds are formed in many compounds e.g., H2O, HF, NH3. The boiling point of such compounds depends to a large extent on the strength of hydrogen bond and the number of hydrogen bonds. The correct decreasing order of the boiling points of the above compounds is :
[A] HF > H2O > NH3
[B] H2O > HF > NH3
[C] NH3 > HF > H2O
[D] NH3 > H2O > HF
Answer: H2O > HF > NH3
(8) The types of hybrid orbitals of nitrogen in NO2+, NO3- and NH4+respectively are expected to be
[A] sp, sp3 and sp2
[B] sp, sp2 and sp3
[C] sp2, sp and sp3
[D] sp2, sp3 and sp
Answer: sp, sp2 and sp3
(9) Polarity in a molecule and hence the dipole moment depends primarily on electronegativity of the constituent atoms and shape of a molecule. Which of Does the following have the highest dipole moment?
[A] CO2
[B] HI
[C] H2O
[D] SO2
Answer: H2O
(10) Isostructural species are those which have the same shape and hybridisation. Among the given species identify the isostructural pairs.
[A] [NF3 and BF3]
[B] [BF4- and NH4+]
[C] [BCl3 and BrCl3]
[D] [NH3 and NO3-]
Answer: [BF4- and NH4+]
(11) Which one has a pyramidal shape?
[A] SO3
[B] PCl3
[C] CO32-
[D] NO3
Answer: PCl3
(12) pπ– dπ bonding is present in which molecule
[A] SO32-
[B] CO32-
[C] NO3
[D] BO33-
Answer: SO32-
(13) Which of the molecules does not have a permanent dipole moment?
[A] SO3
[B] SO2
[C] H2S
[D] CS2
Answer: CS2
(14) The formal charge and P-O bond order in PO43- respectively are
[A] 0.6, -0.75
[B] -0.75, 1.25
[C] 1.0, -0.75
[D] 1.25, -3
Answer: -0.75, 1.25
(15) Find the pair with sphybridisation of the central molecule
[A] NH3 and NO2
[B] BF3 and NH2
[C] BF3 and NO2
[D] NH2– and H2O
Answer: BF3 and NO2
(16) MX6 is a molecule with octahedral geometry. How many X – M – X bonds are at 180°?
[A] four
[B] two
[C] three
[D] six
Answer: three
(17) Find the molecule with the maximum dipole moment
[A] CH4
[B] NH3
[C] CO2
[D] NF3
Answer: NH3
(18) Sp3d2 hybridization is present in [Co(NH3)63+], find its geometry
[A] octahedral geometry
[B] square planar geometry
[C] tetragonal geometry
[D] tetrahedral geometry
Answer: octahedral geometry
(19) Molecules are held together in a crystal by
[A] hydrogen bond
[B] electrostatic attraction
[C] Van der Waal’s attraction
[D] dipole-dipole attraction
Answer: Van der Waal’s attraction
(20) C-O bond length is minimum in
[A] CO2
[B] CO32-
[C] HCOO
[D] CO
Answer: CO

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