Class 12 Chemistry Chapter 2 Solutions MCQs | Class 12 Chemistry Chapter 2 Solutions Multiple Choice Questions (MCQs) and Answers

(1) Equal volumes of 0.1M AgNO3 and 0.2M NaCl are mixed. The concentration of NO3– ions in the mixture will be
[A] 0.1M
[B] 0.05M
[C] 0.2M
[D] 0.15M
Answer: 0.05M
(2) Which of the following should be done in order to prepare 0.4M NaCl starting with 100ml of 0.3M NaCl?
[A] add 5.85g of NaCl
[B] and 20ml water
[C] add 0.01 mol NaCl
[D] evaporate 10ml of water
Answer: add 0.01 mol NaCl
(3) The volume of 0.025M H3PO4 required to neutralise 25ml of 0.03M Ca(OH)2 is
[A] 20ml
[B] 25ml
[C] 40ml
[D] 50ml
Answer: 20ml
(4) The mole fraction of the solute in one molal aqueous solution is
[A] 0.009
[B] 0.018
[C] 0.027
[D] 0.036
Answer: 0.018
(5) 5 cm3 of acetone is added to 100 cm3 of water, the vapour pressure of water over the solution will be
[A] equal to the vapour pressure of pure water
[B] less than the vapour pressure of pure water
[C] greater than the vapour pressure of pure water
[D] very large
Answer: less than the vapour pressure of pure water
(6) The density of a solution prepared by dissolving 129g of urea in 1000g of water is 1.15g/ml. The molarity of this solution is
[A] 1.78M
[B] 1.02M
[C] 2.05M
[D] 0.50M
Answer: 2.05M
(7) If at a certain temperature the vapour pressure of pure water is 25 mm Hg and that of a very dilute aqueous urea solution is 24.5 mm Hg, the molality of the solution is:
[A] 0.02
[B] 1.2
[C] 1.11
[D] 0.08
Answer: 1.11
(8) The relationship between osmotic pressure at 273K when 10g glucose (P1), 10g urea (P2) and 10g sucrose (P3) are dissolved in 250ml of water is
[A] P1 > P2 > P3
[B] P3 > P1 > P2
[C] P2 > P1 > P3
[D] P2 > P3 > P1
Answer: P2 > P1 > P3
(9) Two liquids X and Y form an ideal solution. At 300K vapour pressure of the solution containing 1mol of X and 3 mol of Y is 550 mm Hg. At the same temperature, if 1 mol of Y is further added to this solution, the vapour pressure of the solution increases by 10 mm Hg. Vapour pressure of X and Y in the pure states will be respectively 500 and 600 200 and 300 Answer: (b)
[A] 300 and 400
[B] 400 and 600
[C] Both Frenkel and Schottky defects
[D] cation excess defect
Answer: 400 and 600
(10) Mixing up equal volumes of 0.1M NaOH and 0.1M CH3COOH yields a solution which is
[A] basic
[B] acidic
[C] neutral
[D] None
Answer: basic
(11) Which of the following possesses physical state of solute and solvent are liquid and solid respectively ?
[A] solution of sugar in water
[B] zinc amalgam
[C] solution of Naphthelene in benzene
[D] brass
Answer: zinc amalgam
(12) Which of the following alternative is correct for physical state of solute and solvent for a solution of camphor in N2 gas ?
[A] solid, gas
[B] solid, liquid
[C] gas, solid
[D] gas, gas
Answer: solid, gas
(13) Which of the following is an example of solid solution ?
[A] interstitial compound of hydrogen and Pd
[B] WC
[C] Zn / Hg
[D] Given all
Answer: Given all
(14) Which of the following pair of solution having same physical state of solute ?
[A] homogenous mixture of chloroform in N2 gas, solution of CO2 in water
[B] brass, sodium amalgam
[C] homogenous mixture of camphor in N2 gas, solution of H2 gas in Pd metal
[D] moist air, solution of ethanol in water
Answer: moist air, solution of ethanol in water
(15) Which of the following pair of solution having same physical state of solvent ?
[A] homogenous mixture of chloroform in N2 gas, solution of CO2 in water
[B] brass, solution of salt in water
[C] homogenous mixture of camphor in N2 gas, moist air
[D] solution of H2 gas in Pd metal, solution of ethanol in water
Answer: homogenous mixture of camphor in N2 gas, moist air
(16) Which of the following pair of solution having different physical state of solute ?
[A] homogenous mixture of chloroform in N2 gas, solution of CO2 in water
[B] brass, homogenous mixture of camphor in N2 gas
[C] sodium amalgam, moist air
[D] solution of H2 gas in Pd metal mixture of N2 and O2
Answer: homogenous mixture of chloroform in N2 gas, solution of CO2 in water
(17) Which of the following pair of solution having different physical state of solvent ?
[A] homogenous mixture of N2 gas in chloroform, mixture of N2 and O2
[B] brass, solution of H2 gas in Pd metal
[C] sodium amalgam, solution of urea in water
[D] solution of CO2 in water, solution of Naphthelene in benzene
Answer: sodium amalgam, solution of urea in water
(18) Which of the following compound possesses maximum solubility in water ?
[A] pentan – 1 - ol
[B] Pentane – 2, 3 – diol
[C] pentane – 1, 2, 3 – triol
[D] Pentane – 1, 2, 3, 4 – tetraol
Answer: Pentane – 1, 2, 3, 4 – tetraol
(19) Which of the following given compound is least soluble in water ?
[A] Hexan – 1 – ol
[B] glycerol
[C] Propane – 1, 3 – diol
[D] ethylene glycol
Answer: Hexan – 1 – ol
(20) To convert molarity into which of the following unit of concentration, does not require density of the solution ?
[A] molality
[B] normality
[C] mole-fraction
[D] % w/w
Answer: normality

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