Coordination Compounds MCQs | Coordination Compounds Objective Type Questions and Answers

(21) Which one of the following statement is incorrect?
[A] Greater the formation of (Kf) of a complex ion, greater is its stability
[B] Greater the positive charge one the central metal ion, greater is the stability of the complex
[C] Greater is the basic character of the ligand, lesser is the stability of the complex
[D] Chelate complexes have high stability constants
Answer: Greater is the basic character of the ligand, lesser is the stability of the complex
(22) Among the following ions which one has the highest paramagnetism
[A] [Cr(H2O)6]3+
[B] [Fe(H2O)6]2+
[C] [Cu(H2O)6]2+
[D] [Zn(H2O)6]2+
Answer: [Fe(H2O)6]2+

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(23) Among the following, the compound that I both paramagnetic and coloured is
[A] K2Cr2O7
[B] (NH4)2[LiCl6]
[C] VOSO4
[D] K3[Cu(CN)4]
Answer: VOSO4
(24) The magnetic moment of [NiX4]2– ion is found to be zero. Then the metal of the complex ion is (X = monodentate anionic ligand).
[A] sp3 hybridized
[B] spd2 hybridised
[C] dsp2 hybridized
[D] All of these
Answer: dsp2 hybridized
(25) Which of the following complex shows ionization isomerism
[A] [Cr(NH3)6]Cl3
[B] [Cr(en)2]Cl2
[C] [Cr(en)3]Cl3
[D] [CoBr(NH3)5]SO4
Answer: [CoBr(NH3)5]SO4
(26) The IUPAC name of Xe[PtF6] is
[A] Hexafluoridoplatinate (VI) xenon
[B] Xenol hexafluoridoplatinate (V)
[C] Xenon hexafluoridoplatinate (VI)
[D] None Of The Above
Answer: Xenol hexafluoridoplatinate (V)
(27) The number of ions formed, when bis (ethane-1, 2-diamine)copper (II) sulpahte is dissolve in water will be:
[A] 1
[B] 2
[C] 3
[D] None Of The Above
Answer: 2
(28) The ______ sphere is enclosed in brackets in formulas for complex species, and it includes the central metal ion plus the coordinated groups.
[A] ligand
[B] donor
[C] oxidation
[D] coordination
Answer: coordination
(29) (Valance Bond Theory) Magnetic measurements indicate that [Co(OH2)6]2+ has 3 unpaired electrons. Therefore, the hybridization of the metal's orbitals in [Co(OH2)6]2+ is:
[A] sp3
[B] sp2d
[C] dsp2
[D] sp3d2
Answer: sp3d2
(30) A molecule that cannot be superimposed on its mirror image is said to exhibit which of the following?
[A] geometrical isomerism
[B] optical isomerism
[C] linkage isomerism
[D] reactive isomerism
Answer: optical isomerism
31 (Crystal Field Theory) Consider the complex ion [Mn(OH2)6]2+ with 5 unpaired electrons. Which response includes all the following statements that are true, and no false statements? I. It is diamagnetic. II. It is a low spin complex. III. The metal ion is a d5 ion. IV. The ligands are weak field ligands. V. It is octahedral.
[A] I, II
[B] III, IV, V
[C] I, IV
[D] II, V
Answer: III, IV, V
32 (Crystal Field Theory) When the valence d orbitals of the central metal ion are split in energy in an octahedral ligand field, which orbitals are raised least in energy?
[A] dxy and dx2-y2
[B] dxy, dxz and dyz
[C] dxz and dyz
[D] None of the above
Answer: dxy, dxz and dyz

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