Chemical Kinetics Multiple Choice Questions and Answers

(1) If 75% of a first order reaction was completed in 60 minutes , 50% of the same reaction under the same conditions would be completed in
[A] 20 minutes
[B] 30 minutes
[C] 35 minutes
[D] 75 minutes
Answer: 30 minutes
(2) The half life period of a radioactive element is 140 days. After 560 days , 1 g of element will be reduced to
[A] (1/2)g
[B] (1/4)g
[C] (1/8)g
[D] (1/16)g
Answer: (1/16)g

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(3) The correct difference between first and second order reactions is that
[A] A first order reaction can be catalysed; a second order reaction cannot be catalysed.
[B] The half life of a first order reaction does not depend on [A0]; the half life of a second order reaction does depend on [A0].
[C] The rate of a first order reaction does not depend on reactant concentrations; the rate of a second order reaction does depend on reactant concentrations.
[D] The rate of a first order reaction does depend on reactant concentrations; the rate of a second order reaction does not depend on reactant concentrations.
Answer: The half life of a first order reaction does not depend on [A0]; the half life of a second order reaction does depend on [A0].
(4) After 2 hours, a radioactive substance becomes (1/16)th of original amount. Then the half life ( in min) is
[A] 60 minutes
[B] 120 minutes
[C] 30 minutes
[D] 15 minutes
Answer: 30 minutes

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