A tetrapeptide, made up of natural amino acids, has alanine as the N-terminal residue which

A tetrapeptide, made up of natural amino acids, has alanine as the N-terminal residue which

Q. A tetrapeptide, made up of natural amino acids, has alanine as the N-terminal residue which is coupled to a chiral amino acid. Upon complete hydrolysis, the tetrapeptide gives glycine, alanine, phenylalanine and leucine. The number of possible sequences of the tetrapeptide is         . Ans: 4.0 to 4.0

A tetrapeptide, made up of natural amino acids, has alanine as the N-terminal residue which Read More »

The absorption maxima of two dyes X and Y are 520 and 460 nm, respectively. The absorbance data of these dyes measured in a 1 cm

The absorption maxima of two dyes X and Y are 520 and 460 nm, respectively. The absorbance data of these dyes measured in a 1 cm

Q. The absorption maxima of two dyes X and Y are 520 and 460 nm, respectively. The absorbance data of these dyes measured in a 1 cm path length cell are given in the table below. Dye solution Absorbance at 460 nm Absorbance at 520 nm X (9 mM) 0.144 0.765 Y (12 mM) 0.912

The absorption maxima of two dyes X and Y are 520 and 460 nm, respectively. The absorbance data of these dyes measured in a 1 cm Read More »

The reaction of equimolar quantities of Fe(CO)5 and OH– gives a complex species X which on further reaction with MnO2

The reaction of equimolar quantities of Fe(CO)5 and OH– gives a complex species X which on further reaction with MnO2

Q. The reaction of equimolar quantities of Fe(CO)5 and OH– gives a complex species X which on further reaction with MnO2 gives species Y. X and Y, respectively, are (A) [Fe(CO)5(OH)]– and Fe2(CO)9 (B) [Fe(CO)4]2– and Mn2(CO)10 (C) [HFe(CO)4]– and Fe2O3 (D) [HFe(CO)4]– and Fe3(CO)12 Ans: [HFe(CO)4]- and Fe3(CO)12

The reaction of equimolar quantities of Fe(CO)5 and OH– gives a complex species X which on further reaction with MnO2 Read More »

Second-order rate constant for the reaction between [Co(NH3)5X]n+ (n = 3 for X = NH3 and H2O

Second-order rate constant for the reaction between [Co(NH3)5X]n+ (n = 3 for X = NH3 and H2O

Q. Second-order rate constant for the reaction between [Co(NH3)5X]n+ (n = 3 for X = NH3 and H2O; n = 2 for X = Cl–) and [Cr(H2O)6]2+ at room temperature varies with the X as (A) NH3 > H2O > Cl–                  (B) Cl– > H2O > NH3 (C) NH3 > Cl– > H2O                    (D) H2O >

Second-order rate constant for the reaction between [Co(NH3)5X]n+ (n = 3 for X = NH3 and H2O Read More »

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