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CBSE Class 12 Chemistry Quiz | CBSE Class 12 Chemistry Multiple Choice Questions(MCQs) & Answers

Questions
1 The molal elevation constant depends upon
A nature of the solvent.
B enthalpy change.
C vapour pressure of the solution.
D nature of solute.

Answer: nature of the solvent.
2 The van’t Hoff factor (i) accounts for
A degree of solubilisation of solute.
B the extent of dissociation of solute.
C the extent of dissolution of solute.
D the degree of decomposition of solution.

Answer: the extent of dissociation of solute.
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3 People add sodium chloride to water while boiling eggs. This is to
A increase the boiling point.
B prevent the breaking of eggs.
C decrease the boiling point.
D make eggs tasty.

Answer: increase the boiling point.
4 Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be
A 0.33
B 0.666
C 0.3 × 10-2
D None

Answer: 0.3 × 10-2
5 Which has the lowest boiling point at 1 atm pressure?
A 0.1 M Urea
B 0.1 M A1Cl3
C 0.1 M KCl
D 0.1 M CaCl2

Answer: 0.1 M Urea
6 The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows
A no deviation from Raoult’s Law.
B positive deviation from Raoult’s Law.
C negative deviation from Raoult’s Law.
D that the solution is unsaturated.

Answer: positive deviation from Raoult’s Law.
7 Out of molality (m), molarity (M), formality (F) and mole fraction (x), those which are independent of temperature are
A m, x
B M, x
C M, m
D F, x

Answer: m, x
8 Mole fraction of glycerine C3H5(OH)3 in solution containing 36 g of water and 46 g of glycerine is
A 0.40
B 0.46
C 0.36
D 0.20

Answer: 0.20
9 In the following question a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
A Assertion and reason both are correct statements and reason is correct explanation for assertion.
B Assertion and reason both are incorrect statements.
C Assertion and reason both are correct statements but reason is not correct explanation for assertion.
D Assertion is correct statement but reason is wrong statement.

Answer: Assertion and reason both are incorrect statements.
10 Relative lowering of vapour pressure is a colligative property because ________ .
A It depends on the concentration of a non electrolyte solute in solution and does not depend on the nature of the solute molecules.
B It depends on the concentration of an electrolyte or nonelectrolyte solute in solution as well as on the nature of solute molecules.
C It depends on the concentration of a non electrolyte solute in solution as well as on the nature of the solute molecules.
D It depends on number of particles of electrolyte solute in solution and does not depend on the nature of the solute particles.

Answer: It depends on the concentration of a non electrolyte solute in solution and does not depend on the nature of the solute molecules.
11 Benzoic acid, when dissolved in benzene, which of the following is correct.
A The benzoic acid will undergo dissociation.
B The benzoic acid will undergo association.
C Observed molar mass of benzoic acid in benzene will less than normal molar mass.
D Observed molar mass of benzoic acid in benzene is more than normal molar mass.

Answer: The benzoic acid will undergo association.
12 Which has the highest freezing point?
A 1 M glucose
B 1 M AlF3
C 1 M NaCl
D 1 M CaCl2

Answer: 1 M glucose
13 The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic pressure of 16.4 atom is (R = 0.082 L atom K-1 mol-1)
A 360 K
B 300 K
C 180 K
D 360°C

Answer: 360 K
14 If molality of dilute solution is doubled, the value of molal depression constant (Kf) will be
A halved
B tripled
C unchanged
D doubled

Answer: unchanged
15 At 100°C, the vapour pressure of a solution of 6.5 g of solute in 100 g of water is 732 mm. If Kb is 0.52 K/m, the boiling point of solution will be [HOTS]
A 102°C
B 103°C
C 101 °C
D 100°C

Answer: 101 °C
16 When 1 mole of benzene is mixed with 1 mole of toluene (vapour pressure of benzene – 12.8 kPa, Toluene = 3.85 kPa)
A The vapour will contain equal amount of benzene and toluene.
B Not enough information is given for prediction.
C The vapour will contain a higher percentage of benzene.
D The vapour will contain higher percentage of toluene.

Answer: The vapour will contain a higher percentage of benzene.
17 What is mole fraction of solute in 1.00 m aqueous solution?
A 0.0354
B 0.0177
C 1.770
D 0.177

Answer: 0.0177
18 Cone. H2SO4 is 98 % H2SO4 by mass has d = 1.84 g cm-3. Volume of acid required to make one litre of 0.1 M H2SO4 is
A 30 mL
B 5.55 mL
C 10 mL
D 20 mL

Answer: 5.55 mL
19 A solution containing 10 g per dm3 of urea (molar mass 60 g mol-1) is isotonic with 5% solution of non-volatile solute, MB of solute is
A 250 g mol-1
B 300 g mol-1
C 350 g mol-1
D 200 g mol-1

Answer: 300 g mol-1
20 The value of Henry’s constant KH is _________ .
A greater for gases with higher solubility.
B greater for gases with lower solubility.
C constant for all gases.
D not related to the solubility of gases.

Answer: greater for gases with lower solubility.

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