MCQ on The P Block Elements for Class 11 With Answers | The P Block Elements MCQs

(1) Identify the correct resonance structures of carbon dioxide from the ones given below :
[A] O – C ≡ O
[B] O = C = O
[C] –O ≡ C – O+
[D] –O – C ≡ O+
Answer: B, D
(2) Assertion (A): If aluminium atoms replace a few silicon atoms in three dimensional network of silicon dioxide, the overall structure acquires a negative charge.

Reason (R) : Aluminium is trivalent while silicon is tetravalent.

[A] Both A and R are correct and R is the correct explanation of A.
[B] Both A and R are correct but R is not the correct explanation of A.
[C] Both A and R are not correct
[D] A is not correct but R is correct.
Answer: Both A and R are correct and R is the correct explanation of A.

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(3) Assertion (A): Silicons are water repelling in nature.

Reason (R) : Silicons are organosilicon polymers, which have (–R2SiO–) as repeating unit.

[A] A and R both are correct and R is the correct explanation of A.
[B] Both A and R are correct but R is not the correct explanation of A.
[C] A and R both are not true.
[D] A is not true but R is true.
Answer: Both A and R are correct but R is not the correct explanation of A.
(4) P4O10 has ______ bridging O atoms
[A] 4
[B] 5
[C] 6
[D] 2
Answer: 6
(5) Which of the statement is incorrect for XeO4 ?
[A] four p𝜋-d𝜋 bonds are present
[B] four sp3 – p 𝜎 bonds are present
[C] It has a tetrahedral shape
[D] It has a square planar shape
Answer: It has a square planar shape
(6) Which of the species has a permanent dipole moment?
[A] SF4
[B] SiF4
[C] BF3
[D] XeF4
Answer: SF4
(7) Oxygen is not released on heating which of the compounds?
[A] (NH4)2Cr2O7
[B] K2Cr2O7
[C] Zn(ClO3)2
[D] KClO3
Answer: (NH4)2Cr2O7
(8) Which is the correct order of decreasing bond dissociation enthalpy?
[A] F2 > Cl2 > Br2 > I2
[B] I2 > Br2 > Cl2 > F2
[C] Cl2 > Br2 > F2 > I2
[D] Br2 > I2 > F2 > Cl2
Answer: Cl2 > Br2 > F2 > I2
(9) S-S bond is present in which of the ion pairs
[A] S2O72-, S2O32-
[B] S4O62-, S2O72-
[C] S2O72-, S2O82-
[D] S4O62-, S2O32-
Answer: S4O62-, S2O32-
(10) In the presence of KF, AlF3 is soluble in HF. Find the complex formed
[A] K3[AlF6]
[B] AlH3
[C] K[AlF3H]
[D] K3[AlF3H3]
Answer: K3[AlF6]
(11) Which is the correct order of decreasing acidity of lewis acids?
[A] BBr> BCl3 > BF3
[B] BF> BCl3 > BBr3
[C] BCl3 > BF3 > BBr3
[D] BBr3 > BF3 > BCl3
Answer: BBr> BCl3 > BF3
(12) Graphite has a structural similarity with
[A] B2H6
[B] B4C
[C] B
[D] BN
Answer: BN
(13) Find the amphoteric oxide
[A] CaO2
[B] CO2
[C] SnO2
[D] SiO2
Answer: SnO2
(14) One mole of magnesium nitride on the reaction with an excess of water gives:
[A] one mole of ammonia
[B] one mole of nitric acid
[C] two moles of ammonia
[D] two moles of nitric acid
Answer: two moles of ammonia
(15) The brown ring test for nitrates depends on
[A] reduction of ferrous sulphate to iron
[B] oxidation of nitric oxide to nitrogen dioxide
[C] the reduction of nitrate to nitric oxide
[D] oxidising action of sulphuric acid
Answer: the reduction of nitrate to nitric oxide
(16) In which of the following arrangements, the sequence is not strictly according to the property written against it?
[A] CO2 < SiO2 < SnO2 < PbO2 : Increasing oxidizing power
[B] HF < HCl < HBr < HI : Increasing acid strength
[C] NH3 < PH3 < AsH3 < SbH3 : Increasing basic strength
[D] B < C < O < N : Increasing first ionization enthalpy
Answer: NH3 < PH3 < AsH3 < SbH3 : Increasing basic strength
(17) The reaction of P4 with X leads selectively to P4O6. The X is
[A] Dry O2
[B] A mixture of O2 and N2
[C] Moist O2
[D] O2 in the presence of aqueous NaOH
Answer: A mixture of O2 and N2
(18) Which noble gas is most abundant in atmosphere?
[A] He
[B] Ne
[C] Ar
[D] Kr
Answer: Ar
(19) Which of the following contains P - O - P bond?
[A] Hypophosphorous acid
[B] Phosphorous acid
[C] Pyrophosphoric acid
[D] Orthophosphoric acid
Answer: Pyrophosphoric acid
(20) In which of the following compounds, nitrogen exhibits highest oxidation state?
[A] N3H
[B] NH2OH
[C] N2H4
[D] NH3
Answer: N3H

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